EPR-spectroscopic and quantum-chemical investigations of the fast protolytic reactions of several alkaloids
| dc.contributor.author | Masalimov, A.S. | |
| dc.contributor.author | Ergalieva, E.M. | |
| dc.contributor.author | Nikolskiy, S.N. | |
| dc.contributor.author | Ralchenko, E.A. | |
| dc.contributor.author | Tur, A.A. | |
| dc.date.accessioned | 2019-03-19T08:22:38Z | |
| dc.date.available | 2019-03-19T08:22:38Z | |
| dc.date.issued | 2014-03-29 | |
| dc.description.abstract | Kinetic and thermodynamic experimental parameters for the reactions of protonation of alkaloids by spin probe 3,6-di-tert-butyl-2-oxyphenoxyl obtained by ESR spectroscopy in a toluene solution are presented. Values of various physico-chemical data obtained by quantum chemical calculations in the «Gaussian-2009» for some alkaloids, such as ionization potential, electron affinity and proton affinity have been calculated. | ru_RU |
| dc.identifier.citation | EPR-spectroscopic and quantum-chemical investigations of the fast protolytic reactions of several alkaloids / A.S.Masalimov [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.24-29. | ru_RU |
| dc.identifier.issn | 0142-0843 | |
| dc.identifier.uri | https://rep.buketov.edu.kz:80//handle/data/4475 | |
| dc.language.iso | en | ru_RU |
| dc.publisher | KSU Publ. | ru_RU |
| dc.relation.ispartofseries | Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series.;№ 1(73)/ 2014 | |
| dc.subject | EPR-spectroscopy | ru_RU |
| dc.subject | spin probe | ru_RU |
| dc.subject | 3,6-di-tert.butyl-2-oxyphenoxyl | ru_RU |
| dc.subject | proton transfer reactions | ru_RU |
| dc.subject | quantum-chemical investigations | ru_RU |
| dc.subject | kinetic basicity | ru_RU |
| dc.subject | alkaloids | ru_RU |
| dc.title | EPR-spectroscopic and quantum-chemical investigations of the fast protolytic reactions of several alkaloids | ru_RU |
| dc.title.alternative | Кейбір алкалоидтардағы протондану реакцияларын ЭПР-спектроскопиялық жəне кванттықхимиялық зерттеу | ru_RU |
| dc.title.alternative | ЭПР-спектроскопические и квантово-химические исследования быстрых протолитических реакций некоторых алкалоидов | ru_RU |
| dc.type | Article | ru_RU |