EPR-spectroscopic and quantum-chemical investigations of the fast protolytic reactions of several alkaloids
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KSU Publ.
Abstract
Kinetic and thermodynamic experimental parameters for the reactions of protonation of alkaloids by spin
probe 3,6-di-tert-butyl-2-oxyphenoxyl obtained by ESR spectroscopy in a toluene solution are presented.
Values of various physico-chemical data obtained by quantum chemical calculations in the «Gaussian-2009»
for some alkaloids, such as ionization potential, electron affinity and proton affinity have been calculated.
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EPR-spectroscopic and quantum-chemical investigations of the fast protolytic reactions of several alkaloids / A.S.Masalimov [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.24-29.