EPR-spectroscopy of the fast proton exchange reactions in solutions
| dc.contributor.author | Masalimov, A.S. | |
| dc.contributor.author | Kurmanova, A.F. | |
| dc.contributor.author | Nikolskiy, S.N. | |
| dc.contributor.author | Ospanov, A.U. | |
| dc.contributor.author | Tur, A.A. | |
| dc.date.accessioned | 2019-03-19T08:39:21Z | |
| dc.date.available | 2019-03-19T08:39:21Z | |
| dc.date.issued | 2014-03-29 | |
| dc.description.abstract | Kinetic parameters of the fast intermolecular proton exchange reactions between radical 3,6-di-tert.butyl-2- oxyphenoxyl and different H-acids in toluene solutions obtained by ESR spectroscopy method are presented. NH-acids have more protolytic reactivity than carboxylic acids. Values of various physico-chemical properties for some H-acids, such as ionization potential, electron affinity, proton affinity and energy of deprotonation were obtained by quantum chemical calculations in the program «Gaussian-2009». | ru_RU |
| dc.identifier.citation | EPR-spectroscopy of the fast proton exchange reactions in solutions / A.S.Masalimov [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.30-35. | ru_RU |
| dc.identifier.issn | 0142-0843 | |
| dc.identifier.uri | https://rep.buketov.edu.kz:80//handle/data/4476 | |
| dc.language.iso | en | ru_RU |
| dc.publisher | KSU Publ. | ru_RU |
| dc.relation.ispartofseries | Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series.;№ 1(73)/ 2014 | |
| dc.subject | EPR-spectroscopy | ru_RU |
| dc.subject | semiquinone radicals | ru_RU |
| dc.subject | H-acids | ru_RU |
| dc.subject | proton exchange reactions | ru_RU |
| dc.subject | quantum-chemical investigations | ru_RU |
| dc.title | EPR-spectroscopy of the fast proton exchange reactions in solutions | ru_RU |
| dc.title.alternative | Ерітінділердегі жылдам протон алмасу реакцияларының ЭПР-спектроскопиясы | ru_RU |
| dc.title.alternative | ЭПР-спектроскопия быстрых реакций протонного обмена в растворах | ru_RU |
| dc.type | Article | ru_RU |