EPR-spectroscopy of the fast proton exchange reactions in solutions
Loading...
Date
Journal Title
Journal ISSN
Volume Title
Publisher
KSU Publ.
Abstract
Kinetic parameters of the fast intermolecular proton exchange reactions between radical 3,6-di-tert.butyl-2-
oxyphenoxyl and different H-acids in toluene solutions obtained by ESR spectroscopy method are presented.
NH-acids have more protolytic reactivity than carboxylic acids. Values of various physico-chemical properties
for some H-acids, such as ionization potential, electron affinity, proton affinity and energy of
deprotonation were obtained by quantum chemical calculations in the program «Gaussian-2009».
Description
Citation
EPR-spectroscopy of the fast proton exchange reactions in solutions / A.S.Masalimov [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.30-35.