On the interaction of electrochemical and physicochemical indicators of d metal complexes with sulfur-containing ligands

Abstract

Redox potentials of metal complexes, refraction values, and polarizability indicators of a donor—organic ligand—have been calculated. Correlation dependences between transition constants of outer sphere complexes to inner sphere ones and redox potentials of complexes, taking into account structural and energetic features of ligands and metal ions, have been established.