Investigation tetranuclear complexes of iron (II) by Mössbauer spectroscopy
| dc.contributor.author | Kassenova, N.B. | |
| dc.contributor.author | Yerkassov, R.Sh. | |
| dc.contributor.author | Baisalova, G.Zh. | |
| dc.date.accessioned | 2019-03-20T09:06:20Z | |
| dc.date.available | 2019-03-20T09:06:20Z | |
| dc.date.issued | 2014-06-30 | |
| dc.description.abstract | A series of Fe (II) complexes, {[(tpma)Fe(-CN)]4}X4 (X = ClO4 –, BF4 –, and PF6 –; tpma = tris(2-pyridylmethyl) amine) were prepared by reacting the {Fe(tpma)}2+ building block with (Bu4N)CN. All three complexes exhibit gradual temperature-driven spin crossover (SCO) associated with the high-spin (HS) lowspin (LS) transition at two out of four metal centers. The evolution of HS and LS Fe (II) ions with temperature was followed by a combination of Mössbauer spectroscopy. | ru_RU |
| dc.identifier.citation | Kassenova, N.B., Yerkassov, R.Sh., Baisalova, G.Zh. Investigation tetranuclear complexes of iron (II) by Mössbauer spectroscopy / N.B.Kassenova, R.Sh.Yerkassov, G.Zh.Baisalova // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 2. - P.21-26. | ru_RU |
| dc.identifier.issn | 0142-0843 | |
| dc.identifier.uri | https://rep.buketov.edu.kz:80//handle/data/4501 | |
| dc.language.iso | en | ru_RU |
| dc.publisher | KSU Publ. | ru_RU |
| dc.relation.ispartofseries | Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series.;№ 2(74)/ 2014 | |
| dc.subject | spin-crossover | ru_RU |
| dc.subject | Fe (II) complexes | ru_RU |
| dc.subject | Mössbauer spectroscopy | ru_RU |
| dc.title | Investigation tetranuclear complexes of iron (II) by Mössbauer spectroscopy | ru_RU |
| dc.title.alternative | Мёссбауэр спектроскопия əдісімен төртядролы темір (II) комплекстерін зерттеу | ru_RU |
| dc.title.alternative | Исследование тетраядерных комплексов железа (II) методом Мёссбауэровской спектроскопии | ru_RU |
| dc.type | Article | ru_RU |
| dcterms.type | Article |