Theoretical study of the medium polarity influence on the OH-acids strength

Simple item page
dc.contributor.authorPustolaikina, I.A.
dc.contributor.authorKutzhanova, K.Zh.
dc.contributor.authorKurmanova, A.F.
dc.contributor.authorBatyrova, E.R.
dc.contributor.authorToleutai, D.K.
dc.date.accessioned2019-03-19T05:52:38Z
dc.date.available2019-03-19T05:52:38Z
dc.date.issued2014-03-29
dc.description.abstractDeprotonation energy for a number of OH-acids theoretically estimated by UHF 6–31G ab initio CPCM methods using Gaussian-2009. Reducing of acids deprotonation energy with increasing of the medium polarity is shown by quantum chemical methods. Theoretical justification of EPR spectroscopic data on decrease of rate of the proton exchange reaction between semiquinone radical 3,6-di-tert-butyl-2-oxyphenoxyl and some carboxylic acids in polar media is given.ru_RU
dc.identifier.citationTheoretical study of the medium polarity influence on the OH-acids strength / I.A.Pustolaikina [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.8-14.ru_RU
dc.identifier.issn0142-0843
dc.identifier.urihttps://rep.buketov.edu.kz:80//handle/data/4471
dc.language.isoenru_RU
dc.publisherKSU Publ.ru_RU
dc.relation.ispartofseriesҚарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series.;№ 1(73)/ 2014
dc.subjectOH-acidsru_RU
dc.subjectsemiquinone radicalsru_RU
dc.subjectprotolytic reactionru_RU
dc.subjectproton exchange reactionru_RU
dc.subjectdeprotonation energyru_RU
dc.subjectsolvationru_RU
dc.subjectacidity and basicityru_RU
dc.subjectquantum chemical calculationsru_RU
dc.subjectab initioru_RU
dc.subjectGaussian-2009ru_RU
dc.titleTheoretical study of the medium polarity influence on the OH-acids strengthru_RU
dc.title.alternativeОН-қышқылдарының күшіне орта полярлығының əсерін теориялық зерттеуru_RU
dc.title.alternativeТеоретическое изучение влияния полярности среды на силу ОН-кислотru_RU
dc.typeArticleru_RU

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Pustolaikina_I_A_8-14.pdf
Size:
737.5 KB
Format:
Adobe Portable Document Format
Description:
Download

License bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

1(73)/2014 - Химия