Invariants of ratio of crystal-mobile, liquid-mobile, and vaporized chaotized particles in solid, liquid, and gas states of substance
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KU Publ.
Abstract
The authors of the article have developed the concept of chaotic particles based on the Boltzmann distribution
over the kinetic energy of the particles’ chaotic motion. This distribution allows to combine the solid, liquid,
and gaseous states of matter with the help of energetic particles called crystal-mobile, liquid-mobile, and vapor-
mobile. The ratio of the proportions of such randomized particles determines a certain state of matter aggregation.
The sum of the shares of these particles in all combinations at any temperature is equal to unity.
During the study it has identified that qualitative and quantitative analysis of states with a priority basic effect
of a randomized component of a substance can be conducted. Certain regularities of states were discovered,
independent of the specific type of substance and consistent with the physicochemical properties. The entropy
of mixing of all three energy classes of chaotic particles was calculated for simple substances. It was characterized
by a maximum in the interval of the boiling point of substances. This feature testifies to the unique variety
of possibilities for the implementation of the most complex heterogeneous processes in terrestrial conditions
at atmospheric pressure, which ultimately ensured the self-organization of life.
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Malyshev V.P. Invariants of ratio of crystal-mobile, liquid-mobile, and vaporized chaotized particles in solid, liquid, and gas states of substance/V.P. Malyshev, A.M. Makasheva, L.A. Bekbayeva//Қарағанды университетінің хабаршысы. Химия сериясы.= Вестник Карагандинского университета. Серия Химия. = Bulletin of the Karaganda University. Chemistry Series. -2021. №4. Р.69-78.